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Question

The heat transfer Q, the work done W and the change in internal energy U are all zero in the case of

A.

A rigid vessel containing steam at left in the atmosphere which is at 25o C  

B.

1 kg of gas contained in an insulated cylinder expanding as the piston moves slowly outwards

C.

A rigid vessel containing ammonia gas connected through a valve to an evacuated rigid vessel, the vessel, the valve and the   connecting pipes being well insulated and the valve being opened and after a time, condition through the two vessels becoming uniform

D.

1 kg of air flowing adiabatically from the atmosphere into a previously evacuated bottle

Answer ( Option C)

A rigid vessel containing ammonia gas connected through a valve to an evacuated rigid vessel, the vessel, the valve and the   connecting pipes being well insulated and the valve being opened and after a time, condition through the two vessels becoming uniform

Solution

Ÿ          Evacuated rigid vessel means work done ‘W’ will be zero.

Ÿ          The vessel, the valve end and the connecting pipes being well insulated means heat transfer ‘Q’ will be zero.

From 1st law of thermodynamics,

 

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